Strontium

rubidium ← strontium → yttrium
Ca
↑
Sr
↓
Ba
Appearance
silvery white metallic
General properties
Name, symbol, number strontium, Sr, 38
Pronunciation /ˈstrɒnʃiəm/
stron-shee-əm;
/ˈstrɒntiəm/
stron-tee-əm;
/ˈstrɒnʃəm/ stron-shəm
Element category alkaline earth metal
Group, period, block 2, 5, s
Standard atomic weight 87.62
Electron configuration [Kr] 5s2
Electrons per shell 2, 8, 18, 8, 2 (Image)
Physical properties
Phase solid
Density (near r.t.) 2.64 g·cm−3
Liquid density at m.p. 2.375 g·cm−3
Melting point 1050 K, 777 °C, 1431 °F
Boiling point 1655 K, 1382 °C, 2520 °F
Heat of fusion 7.43 kJ·mol−1
Heat of vaporization 136.9 kJ·mol−1
Molar heat capacity 26.4 J·mol−1·K−1
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 796 882 990 1139 1345 1646
Atomic properties
Oxidation states 2, 1[1] (strongly basic oxide)
Electronegativity 0.95 (Pauling scale)
Ionization energies 1st: 549.5 kJ·mol−1
2nd: 1064.2 kJ·mol−1
3rd: 4138 kJ·mol−1
Atomic radius 215 pm
Covalent radius 195±10 pm
Van der Waals radius 249 pm
Miscellanea
Crystal structure face-centered cubic
Magnetic ordering paramagnetic
Electrical resistivity (20 °C) 132 nΩ·m
Thermal conductivity 35.4 W·m−1·K−1
Thermal expansion (25 °C) 22.5 µm·m−1·K−1
Shear modulus 6.1 GPa
Poisson ratio 0.28
Mohs hardness 1.5
CAS registry number 7440-24-6
Most stable isotopes
Main article: Isotopes of strontium
iso NA half-life DM DE (MeV) DP
82Sr syn 25.36 d ε - 82Rb
83Sr syn 1.35 d ε - 83Rb
β+ 1.23 83Rb
γ 0.76, 0.36 -
84Sr 0.56% 84Sr is stable with 46 neutrons
85Sr syn 64.84 d ε - 85Rb
γ 0.514D -
86Sr 9.86% 86Sr is stable with 48 neutrons
87Sr 7.0% 87Sr is stable with 49 neutrons
88Sr 82.58% 88Sr is stable with 50 neutrons
89Sr syn 50.52 d ε 1.49 89Rb
β− 0.909D 89Y
90Sr trace 28.90 y β− 0.546 90Y
· r

Strontium ( /ˈstrɒntiəm/ stron-tee-əm) is a chemical element with the symbol Sr and the atomic number 38. An alkaline earth metal, strontium is a soft silver-white or yellowish metallic element that is highly reactive chemically. The metal turns yellow when exposed to air. It occurs naturally in the minerals celestine and strontianite. While natural strontium is stable, the synthetic 90Sr isotope is present in radioactive fallout and has a half-life of 28.90 years. Both strontium and strontianite are named after Strontian, a village in Scotland near which the mineral was first discovered.

Contents

Characteristics

Strontium is a grey, silvery metal that is softer than calcium and even more reactive in water, with which it reacts on contact to produce strontium hydroxide and hydrogen gas. It burns in air to produce both strontium oxide and strontium nitride, but since it does not react with nitrogen below 380 °C, at room temperature it will only form the oxide spontaneously.[2]

Because of its extreme reactivity with oxygen and water, this element occurs naturally only in compounds with other elements, such as in the minerals strontianite and celestite. It is kept under a liquid hydrocarbon such as mineral oil or kerosene to prevent oxidation; freshly exposed strontium metal rapidly turns a yellowish color with the formation of the oxide. Finely powdered strontium metal is pyrophoric meaning it will ignite spontaneously in air at room temperature. Volatile strontium salts impart a bright red color to flames, and these salts are used in pyrotechnics and in the production of flares. Natural strontium is a mixture of four stable isotopes.[2]

History

Strontium is named after the Scottish village of Strontian (Gaelic Sron an t-Sithein), having been discovered in the ores taken from the lead mines.[3] In 1790, Adair Crawford, a physician engaged in the preparation of barium, recognised that the Strontian ores exhibited different properties to those normally seen with other "heavy spars" sources.[4] This allowed him to conclude "... it is probable indeed, that the scotch mineral is a new species of earth which has not hitherto been sufficiently examined". The new mineral was named strontites in 1793 by Thomas Charles Hope, a professor of chemistry at the University of Glasgow.[5][6] He confirmed the earlier work of Crawford and recounted: " ... Considering it a peculiar earth I thought it necessary to give it an name. I have called it Strontites, from the place it was found; a mode of derivation in my opinion, fully as proper as any quality it may possess, which is the present fashion". The element was eventually isolated by Sir Humphry Davy in 1808 by the electrolysis of a mixture containing strontium chloride and mercuric oxide, and announced by him in a lecture to the Royal Society on 30 June 1808.[7] In keeping with the naming of the other alkaline earths, he changed the name to strontium.[8][9][10][11]

The first large scale application of strontium was in the production of sugar from sugar beet. Although a crystallisation process using strontium hydroxide was patented by Augustin-Pierre Dubrunfaut in 1849[12] the large scale introduction came with the improvement of the process in the early 1870s. The German sugar industry used the process well into the 19th century. Prior to World War I the beet sugar industry used 100,000 to 150,000 tons of strontium hydroxide for this process per year.[13] The strontium hydroxide was recycled in the process, but the demand to substitute losses during production was high enough to create a significant demand initiating mining of strontianite in the Münsterland. The mining of strontianite in Germany ended when mining of the celestite deposits in Gloucestershire started.[14] These mines supplied most of the world strontium supply from 1884 to 1941 [15]

Occurrence

Strontium commonly occurs in nature, the 15th most abundant element on earth, averaging 0.034% of all igneous rock and is found chiefly as the form of the sulfate mineral celestite (SrSO4) and the carbonate strontianite (SrCO3). Of the two, celestite occurs much more frequently in sedimentary deposits of sufficient size to make development of mining facilities attractive. Because strontium is used most often in the carbonate form, strontianite would be the more useful of the two common minerals, but few deposits have been discovered that are suitable for development.[16]

Strontium metal can be prepared by electrolysis of melted strontium chloride mixed with potassium chloride:

Sr2+ + 2 e−
 → Sr
2 Cl− → Cl2 (g) + 2 e−

Alternatively it is made by reducing strontium oxide with aluminium in a vacuum at a temperature at which strontium distills off.

Three allotropes of metallic strontium exist, with transition points at 235 and 540 °C.

According to the British Geological Survey, China was the top producer of strontium in 2007, with over two-thirds world share, followed by Spain, Mexico, Turkey, Argentina, and Iran.[17]

Isotopes

Main article: Isotopes of strontium

Strontium has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Only 87Sr is radiogenic; it is produced by decay from the radioactive alkali metal 87Rb, which has a half-life of 4.88 × 1010 years. Thus, there are two sources of 87Sr in any material: that formed in stars along with 84Sr, 86Sr and 88Sr, as well as that formed by radioactive decay of 87Rb. The ratio 87Sr/86Sr is the parameter typically reported in geologic investigations; ratios in minerals and rocks have values ranging from about 0.7 to greater than 4.0. Because strontium has an atomic radius similar to that of calcium, it readily substitutes for Ca in minerals.

Sixteen unstable isotopes are known to exist. Of greatest importance are 90Sr with a half-life of 28.78 years and 89Sr with a half-life of 50.5 days. 90Sr is a by-product of nuclear fission found in nuclear fallout and presents a health problem since it substitutes for calcium in bone, preventing expulsion from the body. This isotope is one of the best long-lived high-energy beta emitters known, and is used in SNAP (Systems for Nuclear Auxiliary Power) devices. These devices hold promise for use in spacecraft, remote weather stations, navigational buoys, etc., where a lightweight, long-lived, nuclear-electric power source is required. The 1986 Chernobyl nuclear accident contaminated a vast area with 90Sr. 90Sr confined inside a concave silver plaque is also used for the medical treatment of a resected pterygium.[2]

89Sr is a short-lived artificial radioisotope that is used in the treatment of bone cancer. In circumstances where cancer patients have widespread and painful bony metastases (secondaries), the administration of 89Sr results in the delivery of radioactive emissions (beta particles in this case) directly to the area of bony problem (where calcium turnover is greatest). The 89Sr is manufactured as the chloride salt (which is soluble), and when dissolved in normal saline can be injected intravenously. Typically, cancer patients will be treated with a dose of 150 MBq. Patients must take precautions following this because their urine becomes contaminated with radioactivity, so they must sit to urinate and double-flush the toilet. The beta particles travel about 3.5 mm in bone (energy 0.583 MeV) and 6.5 mm in tissue, so there is no requirement to isolate patients having been treated, except to say they should not have any one (especially young children) sitting in their laps for 10–40 days. The variation in time results from the variable clearing time for 89Sr, which depends on renal function and the number of bony metastases. With a lot of bony metastases, the entire 89Sr dose can be taken up into bone and so the radioactivity is retained to decay over a 50.5-day half-life. It takes about 10 half-lives or about 500 days for 99.9% of the radioactive strontium to decay. However, where there are few bony metastases, the large proportion of 89Sr not taken up by the bone will be filtered by the kidney, so that the effective half-life (a combination of the physical and biological half-life) will be much shorter.

Applications

Strontium carbonate or other strontium salts are used in the manufacture of fireworks, as they impart a deep red color to the firework.[18]

Strontium metal is used in strontium 90%-aluminium 10% alloys of an eutectic composition for the modification of aluminium-silicon casting alloys.[19] AJ62, a durable, creep-resistant magnesium alloy used in car and motorcycle engines by BMW, contains 2% strontium by weight.[20]

Strontium is used in scientific studies of neurotransmitter release in neurons. Like calcium, strontium facilitates synaptic vesicle fusion with the synaptic membrane. But, unlike calcium, strontium causes asynchronous vesicle fusion. Therefore, replacing calcium in a culture medium with strontium allows scientists to measure the effects of a single-vesicle fusion event, e.g., the size of the postsynaptic response elicited by the neurotransmitter content of a single vesicle.[21][22]

Compounds

The primary use for strontium compounds is in glass for colour television cathode ray tubes to prevent X-ray emission.[23][24] All parts of the CRT tube have to absorb X-rays. In the neck and the funnel of the tube, lead glass is used for this purpose, but this type of glass shows a browning effect due to the interaction of the X-rays with the glass. Therefore, the front panel has to use a different glass mixture, in which strontium and barium are the X-ray-absorbing materials. The average values for the glass mixture determined for a recycling study in 2005 is 8.5% strontium oxide and 10% barium oxide.[25]

Other applications are as follows:

Radioactive strontium isotopes

89Sr is the active ingredient in Metastron (the generic version of Metastron, Generic Strontium Chloride Sr-89 Injection, its manufactured by Bio-Nucleonics Inc.[27]), a radiopharmaceutical used for bone pain secondary to metastatic bone cancer. The strontium acts like calcium and is preferentially incorporated into bone at sites of increased osteogenesis. This localization focuses the radiation exposure on the cancerous lesion.

90Sr has been used as a power source for radioisotope thermoelectric generators (RTGs). 90Sr produces about 0.93 watts of heat per gram (it is lower for the form of 90Sr used in RTGs, which is strontium fluoride).[28] However, 90Sr has a lifetime approximately 3 times shorter and has a lower density than 238Pu, another RTG fuel. The main advantage of 90Sr is that it is cheaper than 238Pu and is found in nuclear waste. Soviet Union deployed nearly 1000 of these RTGs on the northern coast as power source for lighthouses and meteorology stations.[29]

90Sr is also used in cancer therapy. Its beta emission and long half-life is ideal for superficial radiotherapy.

Because strontium is so similar to calcium, it is incorporated in the bone. All four stable isotopes are incorporated, in roughly similar proportions, as they are found in nature (please see below). However, the actual distribution of the isotopes tends to vary greatly from one geographical location to another. Thus, analyzing the bone of an individual can help determine the region it came from. This approach helps to identify the ancient migration patterns as well as the origin of commingled human remains in battlefield burial sites. Strontium, thus, helps forensic scientists too.

87Sr/86Sr ratios are commonly used to determine the likely provenance areas of sediment in natural systems, especially in marine and fluvial environments. Dasch (1969) showed that surface sediments of Atlantic displayed 87Sr/86Sr ratios that could be regarded as bulk averages of the 87Sr/86Sr ratios of geological terranes from adjacent landmasses.[30] A good example of a fluvial-marine system to which Sr isotope provenance studies have been successfully employed is the River Nile-Mediterranean system,[31] Due to the differing ages of the rocks that constitute the majority of the Blue and White Nile, catchment areas of the changing provenance of sediment reaching the River Nile delta and East Mediterranean Sea can be discerned through Sr isotopic studies. Such changes are climatically controlled in the Late Quaternary.

More recently, 87Sr/86Sr ratios have also been used to determine the source of ancient archaeological materials such as timbers and corn in Chaco Canyon, New Mexico.[32][33] 87Sr/86Sr ratios in teeth may also be used to track animal migrations [34][35] or in criminal forensics.

Effect on the human body

The human body absorbs strontium as if it were calcium. Due to the chemical similarity of the elements, the stable forms of strontium might not pose a significant health threat — in fact, the levels found naturally may actually be beneficial (see below) - but the radioactive 90Sr can lead to various bone disorders and diseases, including bone cancer. The strontium unit is used in measuring radioactivity from absorbed 90Sr.

A recent in-vitro study conducted the NY College of Dental Sciences using strontium on osteoblasts showed marked improvement on bone-building osteoblasts.[36]

The drug strontium ranelate, made by combining strontium with ranelic acid, was found to aid bone growth, increase bone density, and lessen vertebral, peripheral, and hip fractures.[37][38] Women receiving the drug showed a 12.7% increase in bone density. Women receiving a placebo had a 1.6% decrease. Half the increase in bone density (measured by X-ray densitometry) is attributed to the higher atomic weight of Sr compared with calcium, whereas the other half a true increase in bone mass. Strontium ranelate is registered as a prescription drug in Europe and many countries worldwide. It must be prescribed by a doctor, must be delivered by a pharmacist, and requires strict medical supervision.

There is a long history of medical research regarding strontium's benefits, beginning in the 1950s. Studies indicate a lack of undesirable side-effects.[39][40][41][42][43][44] Several other salts of strontium such as strontium citrate and strontium carbonate are available in the United States under the Dietary Supplements Health and Education Act of 1994, providing close to the recommended strontium content, about 680 milligrams per day, of strontium ranelate. Their long-term safety and efficacy have not been evaluated on humans in large-scale medical trials.

See also

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References

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  3. ^ Murray, W. H. (1977). The Companion Guide to the West Highlands of Scotland. London: Collins. ISBN 0002111357. 
  4. ^ Adair Crawford (1790) "On the medicinal properties of the muriated barytes," Medical Communications (London), vol. 2, pages 301-359.
  5. ^ Although Thomas C. Hope had investigated strontium ores since 1791, he research was published in: Thomas Charles Hope (1798) "Account of a mineral from Strontian and of a particular species of earth which it contains," Transactions of the Royal Society of Edinburg, vol. 4, no. 2, pages 3-39.
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H   He
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K Ca   Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
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Alkali metals Alkaline earth metals Lanthanides Actinides Transition metals Post-transition metals Metalloids Other nonmetals Halogens Noble gases Unknown chem. properties
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Chemical elements named after places
Named after terrestrial places
Magnesium  • Scandium  • Copper  • Gallium  • Germanium  • Strontium  • Yttrium  • Ruthenium  • Tellurium  • Europium  • Terbium  • Holmium  • Erbium  • Thulium  • Ytterbium  • Lutetium  • Hafnium  • Rhenium  • Polonium  • Francium  • Americium  • Berkelium  • Californium  • Dubnium  • Hassium  • Darmstadtium
Named after astronomical objects
Helium  • Selenium • Palladium  • Cerium  • Uranium  • Neptunium  • Plutonium